Sofia Vergara in Vera Wang

Sofia Vergara wins for the evening’s bombshell in a custom teal Vera Wang gown with train for the taking.

Salma Hayek in Gucci

Sexy Salma Hayek’s fiery personality was the perfect compliment to Gucci’s art deco-inspired black and gold gown.

Michelle Williams in Jason Wu

Michelle Williams looked cute and classy in a textured Jason Wu T-shirt gown — a first red carpet appearance for the designer at the Globes.

Julianne Moore in Chanel Haute Couture

Julianne Moore showed her accessorizing chops in a black curve-enhancing Chanel gown offset by green fringe earrings and her signature red locks

Emma Stone in Lanvin

This two-tone Lanvin dress was made for swooshing down the red carpet and Emma Stone continued in her stride as the fashion set’s favorite.

Shailene Woodley in Marchesa

Shailene Woodley wins for newcomer of the evening in a subtley sparkly Marchesa gown that was age-appropriate, yet completely ahead of her generation.

Charlize Theron in Dior Couture

Charlize Theron stunned in a peplum bustled nude Dior gown with a sexy slit placed perfectly to show off her Givenchy sandals.

Tilda Swinton in Haider Ackerman

Tilda Swinton‘s Haider Ackerman ensemble wins accolades for its breathtaking hue alone and the sweeping train and tailored jacket simply add to its originality.

Rooney Mara in Nina Ricci

Hot off Nina Ricci’s Pre-Fall 2012 runway, Rooney Mara stayed in character in a dramatic black cut-out gown, but the overall effect was utterly glamorous.

Angelina Jolie in Atelier Versace

One half of Hollywood’s ruling power couple, Angelina Jolie upped her usual classic elegance in a Versace gown with just the perfect touches of siren red. Matching your bag, lipstick and shoes to your dress just got chic again.